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author:

Lin, C.-X. (Lin, C.-X..) [1] | Zhan, H.-Y. (Zhan, H.-Y..) [2] | Liu, M.-H. (Liu, M.-H..) [3] | Fu, S.-Y. (Fu, S.-Y..) [4] | Huang, L.-H. (Huang, L.-H..) [5]

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Scopus

Abstract:

Acrylic acid(AA) was grafted onto cellulose in homogeneous media by using ammonium persulfate as an initiator in the presence of N,N0- methylenebisacrylamide as a crosslinker under microwave (MW) irradiation. The powerful and highly efficient direct solvent, 1-butyl-3-methylinidazolium chloride ionic liquid was used as the solvent for the dissolution of cellulose and the media for the homogeneous graft polymerization of AA onto cellulose. The use of MW resulted in a drastic reduction of reaction time: 3 min irradiation was sufficient, compared with 30 min to 5 h, as conventional heating was used. Investigation was conducted on the effect of reaction parameters, such as monomer concentration, crosslinker dosage, exposure temperature and exposure time. The structure of the graft copolymer was confirmed by IR spectrum, thermogravimetric analyzer, and scanning electron microscope. The results show that the MW irradiation method can increase the reaction rate. And the graft copolymer is also an effective metal ion adsorbent. © 2010 Wiley Periodicals, Inc.

Keyword:

Acrylic acid; Cellulose; Graft compolymerization; Ionic liquids; Microwave

Community:

  • [ 1 ] [Lin, C.-X.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
  • [ 2 ] [Zhan, H.-Y.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
  • [ 3 ] [Liu, M.-H.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
  • [ 4 ] [Liu, M.-H.]College of Environment and Resources, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 5 ] [Fu, S.-Y.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
  • [ 6 ] [Huang, L.-H.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Reprint 's Address:

  • [Zhan, H.-Y.]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

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Source :

Journal of Applied Polymer Science

ISSN: 0021-8995

Year: 2010

Issue: 1

Volume: 118

Page: 399-404

1 . 2 4

JCR@2010

2 . 7 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 32

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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