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author:

Zheng, M. (Zheng, M..) [1] | Liu, X. (Liu, X..) [2] | Cheng, X. (Cheng, X..) [3]

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Abstract:

Graft copolymerization of maleic anhydrideon (MAH) onto enzymatic hydrolysis lignin (EHL) was carried out with sodium hydroxide aqueous solution as solvent and potassium persulfate-sodium bisulfite (K2S 2O8-NaHSO3) as initiator. The graft ratio and graft efficiency of the copolymer were systematically investigated through changes in the reaction temperature, reaction time, MAH concentration and initiator concentration. The grafted copolymer was further characterized by FTIR and UV-visible spectroscopy. It was found that the graft ratio and graft efficiency varied significantly with the above-mentioned reaction parameters. The optimum conditions for the graft copolymerization were as follows: initiator K2S2O8-NaHSO3 with a quantity 2.5% of lignin, MAH′. EHL (mass fraction) = 0.12, reaction time was 3.5h and temperature at 60°C. In the scope of this experiment, the graft ratio and graft efficiency were respectively obtained up to 5.34% and 80.08%. The fact verified that EHL has better chemical activity. © 2010 American Institute of Physics.

Keyword:

Enzymatic hydrolysis lignin (EHL); Graft polymerization; Maleic anhydride (MAH)

Community:

  • [ 1 ] [Zheng, M.]College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Liu, X.]College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Cheng, X.]College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China

Reprint 's Address:

  • [Cheng, X.]College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

AIP Conference Proceedings

ISSN: 0094-243X

Year: 2010

Volume: 1251

Page: 328-331

Language: English

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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