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author:

Lin, X.-Y. (Lin, X.-Y..) [1] | Zhang, Y. (Zhang, Y..) [2] | Li, R.-L. (Li, R.-L..) [3] | Zhan, Y.-Y. (Zhan, Y.-Y..) [4] | Chen, C.-Q. (Chen, C.-Q..) [5] | Yin, L. (Yin, L..) [6]

Indexed by:

Scopus PKU CSCD

Abstract:

The catalytic properties of ZnO-modified copper ferrite in water-gas shift (WGS) reaction were evaluated between 250 and 400 ℃. The Zn2.5-Cu/Fe (modified by 2.5% ZnO) showed high catalytic activity. The catalyst was characterized with XRD, SEM, H2-TPR and CO2-TPD techniques and N2 sorption experiment. It was shown that introduction of appropriate amounts of ZnO transformed the CuFe2O4 from the tetrahedral crystalline phase to the cubic, enhanced the CuFe2O4 reducibility, and increased the amount of weak and medium basic sites. As a consequence, the interaction between copper and iron species was improved and the catalytic activity was increased. ©, 2014, Science Press. All right reserved.

Keyword:

Basicity; Copper ferrite; Reducibility; WGS reaction; ZnO modification

Community:

  • [ 1 ] [Lin, X.-Y.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Zhang, Y.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Li, R.-L.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Zhan, Y.-Y.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Chen, C.-Q.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Yin, L.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address:

  • [Lin, X.-Y.]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou UniversityChina

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

Year: 2014

Issue: 11

Volume: 42

Page: 1351-1356

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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