• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Cai, J. (Cai, J..) [1] | Huang, Y. (Huang, Y..) [2] | Huang, B. (Huang, B..) [3] | Zheng, S. (Zheng, S..) [4] | Guo, Y. (Guo, Y..) [5]

Indexed by:

Scopus

Abstract:

Pt nanoparticles deposited on manganese oxide-carbon nanotubes (Pt/MnO x-CNTs) are prepared by a microwave-assisted polyol method. Their structure characterizations are carried out by Fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) measurements, indicating that MnOx nanoparticles cover the surface of CNTs and then Pt nanoparticles are uniformly dispersed on MnO x-CNTs with the average particle size of about 2.2 nm. Ethanol oxidation peak current on Pt/MnOx-CNTs (1141.4 mA mg-1 Pt) is 1.82 times higher than that on Pt/CNTs (626.4 mA mg-1 Pt) and 1.28 times higher than that on PtRu/C (JM) (888.6 mA mg-1 Pt). The Pt/MnOx-CNT catalyst presents not only excellent electrocatalytic activity and very high stability for ethanol oxidation, but also high tolerance to the poisonous carbonaceous intermediates generated during ethanol oxidation compared to Pt/CNT catalyst. This is attributed to the excellent proton conductivity of MnOx and the synergistic effect between Pt and MnOx. The optimum mass ratio of MnOx to CNTs is 1:1 in the Pt/MnOx-CNT catalysts. Copyright © 2013, Hydrogen Energy Publications, LLC.

Keyword:

Ethanol oxidation; Fuel cells; Manganese oxides; Microwave method; Platinum nanoparticles

Community:

  • [ 1 ] [Cai, J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Huang, Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Huang, B.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Zheng, S.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 5 ] [Guo, Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

Reprint 's Address:

  • [Guo, Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

Show more details

Related Keywords:

Related Article:

Source :

International Journal of Hydrogen Energy

ISSN: 0360-3199

Year: 2014

Issue: 2

Volume: 39

Page: 798-807

3 . 3 1 3

JCR@2014

8 . 1 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 46

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Affiliated Colleges:

Online/Total:78/9996810
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1