Synthesis of propargylic and allylic trifluoromethyl selenoethers by copper-mediated trifluoromethylselenolation of propargylic chlorides and allylic bromides - Details

author：

Rong, M. (Rong, M..) ^[1] | Huang, R. (Huang, R..) ^[2] | You, Y. (You, Y..) ^[3] | Weng, Z. (Weng, Z..) ^[4]

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Abstract：

The　copper-mediated　trifluoromethylselenolation　of　propargylic　chlorides　and　allylic　bromides　is　described.　This　approach　provides　a　wide　range　of　propargylic　and　allylic　trifluoromethyl　selenoethers　in　moderate　to　good　yields.　These　results　open　the　way　to　synthesis　strategies　for　various　trifluoromethylselenolated　compounds.　©　2014　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Allylic trifluoromethyl selenoethers; Copper; Propargylic trifluoromethyl selenoethers; Trifluoromethylselenolation; Trifluoromethylthiolation

Community：

[ 1 ] [Rong, M.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Huang, R.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [You, Y.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address：

[You, Y.]Department of Chemistry, Fuzhou UniversityChina

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Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2014

Issue： 46

Volume： 70

Page： 8872-8878

2 . 6 4 1

JCR@2014

2 . 1 0 0

JCR@2023

ESI HC Threshold：268

JCR Journal Grade：2

CAS Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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