Designed synthesis of size-tunable Ag2S nanoclusters via distinguishable C-S bond cleavage reaction of alkyl- and aryl-thiolates - Details

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Chen, H.-Q. (Chen, H.-Q..) ^[1] | He, X. (He, X..) ^[2] | Guo, H. (Guo, H..) ^[3] | Fu, N.-Y. (Fu, N.-Y..) ^[4] | Zhao, L. (Zhao, L..) ^[5]

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Abstract：

We　report　herein　the　synthesis　of　two　different　silver　clusters　of　aryl-　and　alkyl-thiolates.　These　two　cluster　complexes　exhibited　biased　C-S　bond　cleavage　reaction　rates　upon　removing　protective　hexamethylazacalix[6]pyridine　(Py[6])　ligands,　which　was　applied　in　the　fabrication　of　silver　sulfide　nanoclusters　with　variable　and　controllable　sizes.　©　The　Royal　Society　of　Chemistry　2015.

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[ 1 ] [Chen, H.-Q.]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing, 100084, China
[ 2 ] [Chen, H.-Q.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [He, X.]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing, 100084, China
[ 4 ] [Guo, H.]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing, 100084, China
[ 5 ] [Fu, N.-Y.]Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Zhao, L.]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing, 100084, China

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[Zhao, L.]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua UniversityChina

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Dalton Transactions

ISSN： 1477-9226

Year： 2015

Issue： 9

Volume： 44

Page： 3963-3966

4 . 1 7 7

JCR@2015

3 . 5 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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