Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters - Details

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Abstract：

Two　windmill-like　Ag3Cu5　alkynyl　clusters　were　synthesized　and　characterized.　They　display　novel　PL　and　ECL　properties,　which　could　be　modified　by　changing　the　substituent　on　the　alkynyl　ligands.　According　to　the　study　of　electrochemical　behaviours,　ECL　behaviours　and　ECL　emission　spectra　of　the　Ag3Cu5　clusters,　a　possible　ECL　mechanism　was　proposed.　This　journal　is　©　The　Royal　Society　of　Chemistry　2015.

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[ 1 ] [Jiang, Y.]Ministry of Education, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Guo, W.-J.]Ministry of Education, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Kong, D.-X.]Ministry of Education, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Wang, Y.-T.]Ministry of Education, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Wang, J.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Graduate School of CAS, Fuzhou Fujian, 350002, China
[ 6 ] [Wei, Q.-H.]Ministry of Education, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 7 ] [Wei, Q.-H.]Beijing Synchrotron Radiation Laboratory, Institute of High Energy Physics, Beijing, 100039, China
[ 8 ] [Wei, Q.-H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Graduate School of CAS, Fuzhou Fujian, 350002, China

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[Wei, Q.-H.]Ministry of Education, College of Chemistry, Fuzhou UniversityChina

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Dalton Transactions

ISSN： 1477-9226

Year： 2015

Issue： 9

Volume： 44

Page： 3941-3944

4 . 1 7 7

JCR@2015

3 . 5 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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