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author:

Gu, Q. (Gu, Q..) [1] | Liao, Y. (Liao, Y..) [2] | Yin, L. (Yin, L..) [3] | Long, J. (Long, J..) [4] | Wang, X. (Wang, X..) [5] | Xue, C. (Xue, C..) [6]

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Scopus

Abstract:

Graphitic carbon nitride microsphere photocatalysts were prepared through a template-free solvothermal approach with post-heating treatment. Structural characterization results reveal that the as-prepared sample has the same composition as bulk g-C3N4, but appears as hierarchical microspheres with nanoporous surfaces. Comparing to the bulk g-C3N4, these porous microspheres exhibit narrowed bandgap and lower resistance, which allows more effective visible-light harvesting and more efficient transport and separation of photogenerated charge carriers. Consequently, we observed high rate of photocatalytic H2 production and stronger photocurrent responses under visible light irradiation. Further, the long-term photocatalytic test proved high stability of the prepared nanoporous microsphere for H2 generation. © 2014 Elsevier B.V.

Keyword:

Carbon nitride; Hydrogen production; Microspheres; Photocatalysis; Solvothermal method

Community:

  • [ 1 ] [Gu, Q.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore
  • [ 2 ] [Liao, Y.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore
  • [ 3 ] [Yin, L.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore
  • [ 4 ] [Long, J.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Wang, X.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Xue, C.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore

Reprint 's Address:

  • [Xue, C.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2015

Volume: 165

Page: 503-510

8 . 3 2 8

JCR@2015

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 215

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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