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author:

Wang, Z.-P. (Wang, Z.-P..) [1] | Feng, M.-L. (Feng, M.-L..) [2] | Xie, X.-K. (Xie, X.-K..) [3] | Huang, X.-Y. (Huang, X.-Y..) [4]

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Scopus

Abstract:

Abstract A novel zinc metal-organic framework (MOF) with the combination of 5,5'-(1,4-phenylene)bis(1H-tetrazole) (H2BDT) and 1,3,5-benzenetricarboxylic acid (H3BTC) as the mixed ligands, namely [Me2NH2]4Zn2(BDT)(BTC)2 2DMF (1), has been solvothermally synthesized and characterized. Single-crystal X-ray analysis reveals that the structure of 1 features a pillared-layered three-dimensional (3D) anionic framework of [Zn2(BTC)2(BDT)]n4n-. The luminescent property studies indicated that 1 might be a potential blue-light material. It was found that the introduction of H3BTC could exhibit an obvious influence on the luminescence of 1, which can help us in better designing luminescent MOF materials. © 2015 Elsevier B.V. All rights reserved.

Keyword:

Crystal structure; Luminescence; Metal-organic framework; Mixed ligands; Pillared-layered framework

Community:

  • [ 1 ] [Wang, Z.-P.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
  • [ 2 ] [Wang, Z.-P.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
  • [ 3 ] [Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
  • [ 4 ] [Xie, X.-K.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
  • [ 5 ] [Xie, X.-K.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
  • [ 6 ] [Huang, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

Reprint 's Address:

  • [Huang, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

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Source :

Inorganic Chemistry Communications

ISSN: 1387-7003

Year: 2015

Volume: 56

Page: 102-104

1 . 7 6 2

JCR@2015

4 . 4 0 0

JCR@2023

ESI HC Threshold:265

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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