The　effective　treatment　of　pharmaceutical　and　personal　care　products　(PPCPs)　contained　wastewater　remains　a　significant　but　challenging　task　for　the　environmental　restoration.　In　this　work,　a　novel　Pd@MIL-100(Fe)　nanocomposite　has　been　successfully　fabricated　via　a　facile　alcohol　reduction　approach.　The　resulting　Pd@MIL-100(Fe)　has　exhibited　superior　photoactivity　toward　degradation　of　three　typical　PPCPs,　that　is　theophylline,　ibuprofen　and　bisphenol　A,　under　visible　light　irradiation　(λ≥.　420.　nm).　Its　photoactivity　is　also　much　higher　than　that　of　original-MIL-100(Fe).　Combining　with　photoelectrochemical　analyses,　it　could　be　revealed　that　the　introduction　of　Pd　NPs　would　minimize　the　recombination　of　photogenerated　electron-hole　pairs,　thereby　improving　the　photocatalytic　performance.　Furthermore,　the　effects　of　different　kinds　of　metals,　the　loading　amount　of　noble-metal,　the　pH　value　of　reaction　solution　and　initial　concentration　of　hydrogen　peroxide　on　the　photocatalytic　degradation　activities　have　been　measured　in　detail.　In　addition,　a　possible　photocatalytic　reaction　mechanism　has　been　investigated.　This　work　has　not　only　represented　the　first　example　of　using　the　MOFs　photocatalysts　to　remove　the　aqueous　PPCPs,　but　also　offered　useful　information　on　the　fabrication　of　efficient　MOF　photocatalysts　for　environmental　restoration.　©　2015.