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author:

Suo, Y. (Suo, Y..) [1] | Zhang, Z. (Zhang, Z..) [2] | Yang, X. (Yang, X..) [3]

Indexed by:

Scopus

Abstract:

In this article, kinetics equation of the metal surface oxidation is presented using the perturbation approach. A moving boundary is converted into a fixed one by Landau transformation. The perturbation results show that (1) the solution of the zeroth-order stands for the quasi-steady state and that of the first-order is instantaneous and (2) the reaction rate, diffusion coefficient, and the thickness of the initial oxide layer have important effects on the oxidation kinetics. If the chemical reaction is supposed to be instantaneous, our results are reduced to the classical parabolic law, no matter whether there exists the initial oxide layer or not. Moreover, the kinetic coefficient of the parabolic law is analytically presented. The proposed perturbation scheme can be easily extended to the higher order, and the higher order solution will provide a method to correct the error offered by the classical model. © The Author(s) 2017.

Keyword:

Landau transformation; Metal surface oxidation; oxide kinetics; perturbation approach

Community:

  • [ 1 ] [Suo, Y.]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Suo, Y.]School of Science, Xi'An University of Science and Technology, Xi'an, China
  • [ 3 ] [Suo, Y.]State Key Lab for Strength and Vibration of Mechanical Structures, School of Aerospace, Xi'An Jiaotong University, Xi'an, 710049, China
  • [ 4 ] [Zhang, Z.]School of Science, Xi'An University of Science and Technology, Xi'an, China
  • [ 5 ] [Yang, X.]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address:

  • [Suo, Y.]School of Mechanical Engineering and Automation, Fuzhou UniversityChina

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Source :

Advances in Mechanical Engineering

ISSN: 1687-8132

Year: 2017

Issue: 1

Volume: 9

0 . 8 4 8

JCR@2017

1 . 9 0 0

JCR@2023

ESI HC Threshold:177

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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