Solvothermal synthesis, crystal structure and photoluminescence property of a 3D Lead(II) coordination polymer based on terephthalic acid - Details

author：

Lin, X.-Y. (Lin, X.-Y..) ^[1] | Yang, P. (Yang, P..) ^[2] | Chen, J. (Chen, J..) ^[3] | Liu, M.-H. (Liu, M.-H..) ^[4] | Lin, C. (Lin, C..) ^[5] (Scholars：林诚)

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Scopus CSCD

Abstract：

Solvothermal　reaction　of　Pb(NO3)2.6H2O　with　rigid　linear　ligand　terephthalic　acid　(H2pta)　in　N,N-dimethylformamide　(DMF)　produced　a　new　three-dimensional　(3D)　lead(II)　coordination　polymer　[Pb2(pta)1.5(μ4-OH)(DMF)]n　1,　and　its　structure　was　characterized　by　single-crystal　X-ray　diffraction　analyses.　In　polymer　1,　the　μ4-OH　bridges　the　nearby　lead(II)　ions　into　an　infinite　one-dimensional　(1D)　chain,　and　then　the　organic　ligand　pta2-joins　the　neighbored　chains　into　a　3D　structure　by　two　similar　connection　modes　in　different　configurations.　The　solid-state　photoluminescent　studies　revealed　that　1　exhibits　a　strong　greenish　emission　mainly　originating　from　ligand-to-metal　charge　transfer　between　the　delocalized　π　bonds　of　the　aromatic　carboxylate　ligand　pta2-and　the　p　orbitals　of　the　Pb2+centers.

Keyword：

Crystal structure; Lead(II) coordination polymer; Photoluminescence property; Solvothermal synthesis; Terephthalic acid

Community：

[ 1 ] [Lin, X.-Y.]School of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Lin, X.-Y.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 3 ] [Yang, P.]School of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Chen, J.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 5 ] [Liu, M.-H.]College of Environment and Resources, Fuzhou University, Fuzhou, 350116, China
[ 6 ] [Lin, C.]School of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

林诚
[Lin, C.]School of Chemical Engineering, Fuzhou UniversityChina

Email：

clin@fzu.edu.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2016

Issue： 1

Volume： 35

Page： 61-68

0 . 5 8 3

JCR@2016

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：235

JCR Journal Grade：4

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 3

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

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