Novel lanthanide cluster polymers based on cubane-like [Ln4(OH)4]8+ clusters and sulfate anions - Details

author：

Zhou, L.-L. (Zhou, L.-L..) ^[1] | Ding, L. (Ding, L..) ^[2] | Wei, K.-Y. (Wei, K.-Y..) ^[3] | Sun, Y.-Q. (Sun, Y.-Q..) ^[4] (Scholars：孙燕琼) | Chen, Y.-P. (Chen, Y.-P..) ^[5] (Scholars：陈义平)

Indexed by：

Scopus CSCD

Abstract：

Two　lanthanide-oxo-cluster　polymers　were　synthesized　by　hydrothermal　reaction　using　Ln2O3　as　initial　lanthanide　materials:　[Ln4(SO4)4(OH)4(H2O)7]4H2O　(Ln　=　Er　1,　Ho　2),　and　characterized　by　PXRD,　IR　spectra,　X-ray　single-crystal　diffraction,　2D　IR　correlation　spectra　and　UV-visible　absorption　spectra.　Single-crystal　X-ray　analyses　reveal　that　compounds　1　and　2　are　isostructural,　and　they　are　both　crystallized　in　the　orthorhombic　system　Pccn　space　group.　Compound　1　is　a　3D　lanthanide　cluster　polymer　based　on　tetranuclear　cubane-like　[Er4(μ3-OH)4]8+　cations　and　SO4　2-　anions.　The　overall　structure　of　1　can　be　assigned　to　6-connected　pcu-type　topology　with　the　point　symbol　of　(412.63).

Keyword：

Crystal structure; Lanthanide cluster polymer; Sulfate anion; Tetranuclear lanthanide-oxo-clusters

Community：

[ 1 ] [Zhou, L.-L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Ding, L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 3 ] [Wei, K.-Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Sun, Y.-Q.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Sun, Y.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Chen, Y.-P.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

孙燕琼
[Sun, Y.-Q.]College of Chemistry, Fuzhou UniversityChina

Email：

sunyanqiong@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2016

Issue： 3

Volume： 35

Page： 375-382

0 . 5 8 3

JCR@2016

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：235

JCR Journal Grade：4

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 1

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

Affiliated Colleges：

化学学院本学院/部未明确归属的数据

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to