Synthesis and thermal stability study of a cobalt-organic framework with tetrahedral cages - Details

author：

Lin, X.-Y. (Lin, X.-Y..) ^[1] | Zheng, Q.-Q. (Zheng, Q.-Q..) ^[2] | Liu, X.-Z. (Liu, X.-Z..) ^[3] | Jiang, X.-Y. (Jiang, X.-Y..) ^[4] | Lin, C. (Lin, C..) ^[5]

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Abstract：

A　new　stable　cobalt-organic　framework,　namely　[Co2(oba)2(H2Me4bpz)]n　(1)　(H2oba　=　4.4＇-oxydibenzoic　acid,　H2Me4bpz　=　3.3＇,5,5＇-tetramethyl-4,4＇-bipyrazole),　has　been　synthesized　by　combining　the　mixed　H2oba　and　H2Me4bpz　with　Co(CH3COO)2·4H2O　under　solvothermal　conditions,　which　was　characterized　by　infrared　spectroscopy,　single-crystal　X-ray　diffraction,　powder　X-ray　diffraction,　and　thermogravimetric　analyses.　Single-crystal　X-ray　diffraction　analysis　reveals　that　1　features　a　three-dimensional　framework,　which　is　built　from　interesting　tetrahedral　cages.　The　thermal　stability　of　the　complex　has　also　been　investigated.　©　2016　Elsevier　B.V.　All　rights　reserved.

Keyword：

Cobalt; Crystal structure; Mixed ligand; MOFs; Thermal stability

Community：

[ 1 ] [Lin, X.-Y.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 2 ] [Zheng, Q.-Q.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 3 ] [Liu, X.-Z.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 4 ] [Jiang, X.-Y.]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, China
[ 5 ] [Lin, C.]School of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2016

Volume： 67

Page： 51-54

1 . 6 4

JCR@2016

4 . 4 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：4

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SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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