Pt/FeSnO(OH)5　was　synthesized　as　a　novel　catalyst　for　VOCs　oxidation.　Compared　with　Pt/γ-Al2O3　during　catalytic　oxidation　of　benzene,　Pt/FeSnO(OH)5　showed　better　catalytic　activity.　After　characterization　of　the　catalysts　by　XRD,　SEM,　TEM,　EDS,　XPS,　BET,　TGA　and　DTA,　we　found　most　Pt　could　be　reduced　to　metallic　state　when　the　hydroxyl　catalyst　was　used　as　supporter,　and　the　metallic　Pt　in　Pt/FeSnO(OH)5　was　more　active　than　the　oxidized　Pt　in　Pt/γ-Al2O3　in　catalytic　oxidation　of　VOCs.　Pt/FeSnO(OH)5　shows　both　good　catalytic　activity　and　high　stability,　which　may　be　a　promising　catalyst.　This　study　may　also　be　helpful　for　the　design　and　fabrication　of　new　catalysts.