Solvothermal Synthesis, Crystal Structure and Characterizations of a Novel 2D Organic Decorated Manganese Thiostannate: MnSnS3(1,2-DACH) - Details

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Abstract：

A　novel　1,2-diaminocyclohexane　(1,2-DACH)　decorated　manganese　thiostannate,　namely　MnSnS3(1,2-DACH)　(1),　has　been　solvothermally　synthesized　by　the　reaction　of　Mn(CH3COO)2·4H2O,　Sn　and　S　in　the　stoichiometric　ratio　in　1,2-DACH,　which　acted　as　an　efficient　structure-directing　agent　(SDA)　and　reactive　solvent　in　the　formation　of　the　title　compound.　Single-crystal　X-ray　diffraction　studies　revealed　that　the　title　compound　crystallizes　in　the　monoclinic　space　group　P21/c　with　a　=　12.2458(7),　b　=　13.8588(7),　c　=　7.2292(4)　Å,β　=　99.460(6)o,　V　=　1210.20(12)　Å3,　Z　=　4,　Dc　=　2.108　g·cm-3,　F(000)　=　748,　μ　=　3.584　mm-1,　R　=　0.0348　and　wR　=　0.0823　(I　>　2σ(I)).　The　structure　features　a　neutral　two-dimensional　(2D)　network　constructed　by　the　unsaturated　[Mn(1,2-DACH)]　complexes　interconnecting　[SnS3]n2n-　chains　via　sharing　S.　Thermal　stability　and　optical　property　of　compound　1　were　characterized.

Keyword：

Crystal structure; Manganese thiostannate; Two-dimensional network

Community：

[ 1 ] [Qi, X.-H.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 2 ] [Qi, X.-H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Wu, B.-J.]School of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
[ 4 ] [Du, K.-Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Ye, X.-Y.]School of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
[ 6 ] [Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 7 ] [Huang, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address：

[Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

fml@fjirsm.ac.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2016

Issue： 10

Volume： 35

Page： 1546-1552

0 . 5 8 3

JCR@2016

5 . 9 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：4

CAS Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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