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Abstract:
The title coordination polymer, [Ag2(C10H4O8)(C12H9N3)2] n , was prepared by a hydro-thermal method. The AgI atom exists in a strongly distorted trigonal coordination environment. Two AgI ions related by an inversion centre are coordinated by two 2-(3-pyrid-yl)benzimidazole ligands, forming a centrosymmetric cyclic dimer. The bridging bidentate 2,5-dicarboxy-benzene-1,4-dicarboxyl-ate ligand is also located on an inversion centre and connects the binuclear units, generating a one-dimensional polymer. The almost-planar conformation of this ligand allows it to form a strong intra-molecular O - H⋯O hydrogen bond. Finally, inter-molecular N - H⋯O hydrogen bonds aggregate the chains into a three-dimensional framework.
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Acta Crystallographica Section E: Structure Reports Online
ISSN: 1600-5368
Year: 2008
Issue: 3
Volume: 64
0 . 3 6 7
JCR@2008
0 . 3 4 7
JCR@2011
JCR Journal Grade:4
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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