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Abstract:
The CeIII ion in the title complex, [Ce(NO3)3(C13H12N4O)2], is 12-coordinated by six chelating nitrate O atoms and six donors (2 O and 4 N atoms) of two N'-[1-(2-pyrid-yl)ethyl-idene]isonicotinohydrazide ligands, exhibiting a bicapped penta-gonal-anti-prism-type coordination geometry. The title complex possesses C 2 point symmetry and is located on a twofold crystallographic axis. Each mol-ecule is linked with four surrounding mol-ecules by four N - H⋯N hydrogen bonds, resulting in an extended two-dimensional layer parallel to the ab plane, while π-π inter-actions between pyridine rings from neighboring complex mol-ecules connect the two-dimensional layers into a three-dimensional cerium-organic supra-molecular structure. © 2009 International Union of Crystallography.
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Acta Crystallographica Section C: Crystal Structure Communications
ISSN: 0108-2701
Year: 2009
Issue: 7
Volume: 65
Page: m269-m272
0 . 7 8 2
JCR@2009
0 . 3 2 6
JCR@2014
JCR Journal Grade:3
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