Coordination　compound　derivates　(CCDs)　have　been　widely　applied　in　lithium-ion　batteries　(LIBs).　However,　the　functionalization　of　CCDs　with　open　structure　and　heteroatomic　doping　is　still　challenging.　Herein,　an　effective　functionalization　strategy　is　presented　to　prepare　a　kind　of　CCD,　where　Co0.85Se　nanoparticles　are　encapsulated　by　nitrogen-enriched　hierarchically　porous　carbon　(CS/NPC)　based　on　the　heat　treatment　of　a　cobalt-complexed　hexamethylolmelamine-polyvinylpyrrolidone　resin　(Co2+/HPR).　The　abundant　free　volume　and　enriched　N　species　of　the　HPR　are　responsible　for　the　hierarchically　porous　configuration　and　high　N-doping　of　the　composites.　By　controlling　the　content　of　cobalt　salt　and　the　heating　rate,　high　specific　surface　area　(440.7　m2　g-1),　high　N-doping　(8.54　atom　%),　and　suitable　mass　loading　of　Co0.85Se　(55.5%)　were　simultaneously　achieved　in　CS-2/NPC-5,　which　delivers　high　reversible　capacity　(758.5　mAh　g-1　at　0.1　A　g-1),　outstanding　rate　capability　(401.7　mAh　g-1　at　5　A　g-1),　and　excellent　cycling　durability　(638.4　mAh　g-1　at　1　A　g-1　after　200　cycles),　suggesting　a　promising　candidate　for　LIB　anode　materials.　Copyright　©　2020　American　Chemical　Society.