Hybrid　capacitor　has　attracted　great　interest　owing　to　the　higher　energy　density　compared　with　traditional　double-layer　capacitor.　However,　the　fabrication　of　high-performance　hybrid　aqueous　capacitor　based　on　low-cost　and　multivalent　ion　storage　remains　challenging.　In　this　work,　highly　porous　TiO2　microrods　(P-TiO2-MRs)　with　uniform　and　large　pore　size　are　prepared　extensively　with　a　simple　hydrothermal　synthesis.　Such　micro/nano-structured　anode　exhibit　remarkably　enhanced　Al　ion　intercalation/deintercalation　performance　in　optimized　AlCl3　aqueous　electrolyte.　The　electrode　has　large　discharge　capacity　with　111.1　mAh　g−1　@　1　A　g−1　and　superior　rate　capability　with　49.8　mAh　g−1　@　5　A　g−1.　For　the　first　time,　a　novel　hybrid　device　is　fabricated　through　assembling　insertion-type　P-TiO2-MRs　anode　and　absorption-type　active　carbon　(AC)　cathode　(P-TiO2-MRs//AC)　in　AlCl3　aqueous　electrolyte.　The　fabricated　hybrid　capacitor　delivers　a　high　energy　density　of　26.3　Wh　kg−1　@　627.3　W　kg−1　as　well　as　an　outstanding　high　power　of　5454.5　W　kg−1　@　10.9　Wh　kg−1.　In　addition,　it　also　displays　excellent　rate　capability　and　superior　retention　of　63%　even　after　1000　cycles.　©　2020　Elsevier　B.V.