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author:

Li, Y. (Li, Y..) [1] | Xiang, C. (Xiang, C..) [2] | Su, X. (Su, X..) [3] | Li, S. (Li, S..) [4] | Gu, H. (Gu, H..) [5] | Luo, J. (Luo, J..) [6] | Yin, X. (Yin, X..) [7] | Yu, Z. (Yu, Z..) [8]

Indexed by:

Scopus

Abstract:

The understanding of the microstructures is critical to the design of SiC fibers with excellent thermal stability and mechanical properties. We introduce a density-sensitive electron microscopy method, high-angle annular dark field (HAADF) imaging to study the microstructure of SiC fibers processed at a variety of temperatures ranging from 1200 to 1800 °C. It is revealed that, irrespective of their processing temperatures, SiC grains form the skeleton of SiC fibers that are surrounded by a multiple of zones with low HAADF contrast (low-density zones, LDZs). LDZs mainly consist of amorphous SiOC phases and turbostratic graphite. As a result, three important interfaces that dictate grain growth, namely, the SiC/amorphous SiOC interface, the SiC/turbostratic graphite phase boundary and the SiC high angle grain boundary (HAGBs) emerge. We find that, the SiC/turbostratic graphite interfaces and the SiC HAGBs are more effective in suppressing the growth of SiC grains than the SiC/a-SiOC interfaces on a basis of extensive TEM characterization. Aberration corrected TEM reveals marked differences in the atomic structures of those three interfaces, shedding light on how the interfacial structures affect grain growth of SiC fibers. © 2020 Elsevier Ltd and Techna Group S.r.l.

Keyword:

Electron microscopy; Grain growth; Interfacial structure; Microstructure; SiC fiber

Community:

  • [ 1 ] [Li, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Xiang, C.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Su, X.]Fujian Key Laboratory of Advanced Materials, Key Laboratory of High Performance Ceramic Fibers (Ministry of Education), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 4 ] [Li, S.]Fujian Key Laboratory of Advanced Materials, Key Laboratory of High Performance Ceramic Fibers (Ministry of Education), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 5 ] [Gu, H.]Materials Genome Institute, School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China
  • [ 6 ] [Luo, J.]Department of NanoEngineering, Program of Materials Science and Engineering, University of California, San Diego, La Jolla, CA 92093-0448, United States
  • [ 7 ] [Yin, X.]Science and Technology on Thermostrucutral Composite Materials Laboratory, Northwestern Polytechnical University, Xi'an, 710072, China
  • [ 8 ] [Yu, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 9 ] [Yu, Z.]Xiamen Tungsten Co., LTD, Xiamen, Fujian 361126, China

Reprint 's Address:

  • [Yu, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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Source :

Ceramics International

ISSN: 0272-8842

Year: 2020

Issue: 8

Volume: 46

Page: 10279-10283

4 . 5 2 7

JCR@2020

5 . 1 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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