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author:

Zhang, J. (Zhang, J..) [1] | Zeng, L. (Zeng, L..) [2] | Qiao, Z. (Qiao, Z..) [3] | Wang, J. (Wang, J..) [4] | Jiang, X. (Jiang, X..) [5] | Zhang, Y.S. (Zhang, Y.S..) [6] | Yang, H. (Yang, H..) [7]

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Scopus

Abstract:

Multifunctional hydrogels have important applications in various fields such as artificial muscles, wearable devices, soft robotics, and tissue engineering, especially for those with favorable mechanical properties, good low-temperature resistance, and stimuli-responsive capabilities. In the current study, a type of polyacrylamide/sodium alginate/carbon nanotube (PAAm/SA/CNT) double-network (DN) hydrogel was fabricated, which exhibited a high tensile strength of 271.68 ± 6.04 kPa, a favorable conductivity of 1.38 ± 0.17 S·m-1, and a good self-healing ability under heating conditions. In addition, the composite hydrogel exhibited controllable photomechanical deformations under near-infrared irradiation, such as bending, swelling, swimming, and object grasping. To further broaden the applications of the hydrogel in low-temperature environments, calcium chloride (CaCl2) was introduced into such a PAAm/SA/CNT DN hydrogel as an additive. Interestingly, the tensile/compressive strengths as well as elasticity were well-maintained at a temperature as low as-20 °C. In addition, the PAAm/SA/CNT/CaCl2 hydrogel presented excellent conductivity, recoverability, and strain-sensing capability under such extreme conditions. Overall, the investigations conducted in this paper have provided potentially new methods and inspirations for the generation of multifunctional PAAm/SA/CNT/CaCl2 hybrid DN hydrogels toward extended applications. Copyright © 2020 American Chemical Society.

Keyword:

double-network hydrogel; low-temperature resistance; mechanical performance; photomechanical deformation; strain sensing

Community:

  • [ 1 ] [Zhang, J.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Zhang, J.]Moe Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Zeng, L.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Zeng, L.]Moe Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Qiao, Z.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Qiao, Z.]Moe Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Wang, J.]Moe Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Jiang, X.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 9 ] [Zhang, Y.S.]Division of Engineering in Medicine, Brigham and Women's Hospital, Department of Medicine, Harvard Medical School, Cambridge, MA 02139, United States
  • [ 10 ] [Yang, H.]Moe Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China

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Source :

ACS Applied Materials and Interfaces

ISSN: 1944-8244

Year: 2020

Issue: 27

Volume: 12

Page: 30247-30258

9 . 2 2 9

JCR@2020

8 . 5 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 102

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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