Persistent radical anions in panchromatic D-A hybrid heterostructures induced by anion-π interactions - Details

author：

You, M.-H. (You, M.-H..) ^[1] | Di, Y.-M. (Di, Y.-M..) ^[2] | Li, M.-H. (Li, M.-H..) ^[3] | Li, H.-H. (Li, H.-H..) ^[4] | Lin, M.-J. (Lin, M.-J..) ^[5]

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Abstract：

The　combination　of　N,　N′-dipyridyl-tetrachloroperylene　diimide　(4Cl-DPPDI)　buliding　blocks　with　lead　iodides　in　the　presence　of　hydrogen　iodides　led　to　a　novel　D-A　hybrid　heterostructure　with　segregated　iodoplumbate　anions　and　2-D　H-bonded　4Cl-DPPDI　networks　as　electron　donors　and　acceptors.　Due　to　the　compact　anion-π　interactions　as　well　as　small　energy　gaps　between　the　donors　and　acceptors,　persistent　and　stable　radical　anions　are　generated　in　such　a　unique　complex　triggered　by　natural-light　irradiation,　which　thus　exhibits　a　panchromatic　absorption.　©　2020　Elsevier　Ltd

Keyword：

Anion-π interactions; D-A hybrid heterostructures; Iodoplumbate anions; Perylene diimides; Stable radicals

Community：

[ 1 ] [You, M.-H.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University350116, China
[ 2 ] [You, M.-H.]College of Zhicheng, Fuzhou University350002, China
[ 3 ] [Di, Y.-M.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University350116, China
[ 4 ] [Li, M.-H.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University350116, China
[ 5 ] [Li, H.-H.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University350116, China
[ 6 ] [Lin, M.-J.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University350116, China

Reprint 's Address：

[Lin, M.-J.]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

meijin_lin@fzu.edu.cn

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Source ：

Dyes and Pigments

ISSN： 0143-7208

Year： 2020

Volume： 180

4 . 8 8 9

JCR@2020

4 . 1 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

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