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author:

Wang, Z. (Wang, Z..) [1] | Yang, L. (Yang, L..) [2] | Ye, X. (Ye, X..) [3] | Huang, C. (Huang, C..) [4] | Yang, W. (Yang, W..) [5] | Zhang, L. (Zhang, L..) [6] | Wu, Z. (Wu, Z..) [7] | Fu, F. (Fu, F..) [8]

Indexed by:

Scopus

Abstract:

Dithiocarbamates (DTCs) pesticides were extensively used as fungicides in a variety of crops during their growth, storage and shipment. The DTCs residue in foods will seriously harm human health. In this study, a novel multicolor colorimetric sensor was developed for visual screening of total DTCs (total of ziram, thiram and zineb) based on sulfhydryl-mediated growth of gold nanobipyramids (AuNBPs). We demonstrated that DTCs can absorb on AuNBPs seed's surface via the formation of Au–S bonds and thus impede the 8-hydroxyquinoline (8-HQ)-promoted AuNBPs growth, which generates DTCs concentration-corresponding color changes. The developed sensor has vivid color changes, short analysis time, higher sensitivity and excellent specificity. It can be used to detect as low as 50 nM of total DTCs by bare eye observation and 17–18 nM of total DTCs by UV–visible spectrometry. By using the multicolor sensor, we have successfully screened total DTCs in apple and black tea by bare eye observation, and detected total DTCs in apple and black tea by UV–visible spectrometry with a recovery of 90%–104% and a relative standard deviation (RSD, n = 5) < 5%. The results obtained with our method consisted well with those obtained with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS), verifying that our method had good accuracy and reliability. Especially, the visual detection limit of our method is much lower than the maximum residue limit of total DTCs in vegetable and fruits. All above features make our sensor a promising method for rapid on-site screening of total DTCs in vegetable and fruits by only bare eye observation. © 2020 Elsevier B.V.

Keyword:

Colorimetric sensor; Dithiocarbamates pesticide; Thiram; Zineb; Ziram

Community:

  • [ 1 ] [Wang, Z.]State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 2 ] [Yang, L.]State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 3 ] [Ye, X.]College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 4 ] [Huang, C.]State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 5 ] [Yang, W.]State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 6 ] [Zhang, L.]College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 7 ] [Wu, Z.]State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 8 ] [Fu, F.]Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Lab of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address:

  • [Fu, F.]Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Lab of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, State Key Laboratory of Ecological Pest Control for Fujian and Taiwan Crops, College of Plant Protection, Fujian Agriculture and Forestry UniversityChina

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Source :

Analytica Chimica Acta

ISSN: 0003-2670

Year: 2020

Volume: 1139

Page: 59-67

6 . 5 5 8

JCR@2020

5 . 7 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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