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author:

Wang, L. (Wang, L..) [1] | Sun, J. (Sun, J..) [2] | Guo, W. (Guo, W..) [3] | Dong, Y. (Dong, Y..) [4] | Xie, Y. (Xie, Y..) [5] | Xiong, F. (Xiong, F..) [6] | Du, Z. (Du, Z..) [7] | Li, L. (Li, L..) [8] | Deng, J. (Deng, J..) [9] | Xu, C. (Xu, C..) [10]

Indexed by:

Scopus

Abstract:

Arc discharge is traditionally used to synthesize randomly arranged graphene flakes. In this paper, we substantially modify it into a glow discharge method so that the discharge current is much more reduced. The H2 and/or Ar plasma etching of the graphitic electrode (used to ignite the plasma) is hence much gentler, rendering it possible to grow graphene in thin film format. During the growth at a few mbar, there is no external carbon gas precursor introduced. The carbon atoms and/or carbon containing particles as a result of the plasma etching are emitted in the chamber, some of which undergo gas phase scattering and deposit onto the metallic catalyst substrates (Cu-Ni alloy thin films or Cu foils) as graphene sheets. It is found that high quality monolayer graphene can be synthesized on Cu foil at 900 °C. On Cu-Ni, under the same growth condition, somewhat more bilayer regions are observed. It is observed that the material quality is almost indifferent to the gas ratios, which makes the optimization of the deposition process relatively easy. Detailed study on the deposition procedure and the material characterization have been carried out. This work reveals the possibility of producing thin film graphene by a gas discharge based process, not only from fundamental point of view, but it also provides an alternative technique other than standard chemical vapor deposition to synthesize graphene that is compatible with the semiconductor planar process. As the process uses solid graphite as a source material that is rich in the crust, it is a facile and relatively cheap method to obtain high quality graphene thin films in this respect. © 2020 by the authors.

Keyword:

Chemical vapor deposition; Glow discharge; Graphene; Graphite; Metal catalyst; Plasma; Solid carbon source

Community:

  • [ 1 ] [Wang, L.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Sun, J.]National and Local United Engineering Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350100, China
  • [ 3 ] [Sun, J.]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350100, China
  • [ 4 ] [Guo, W.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Dong, Y.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Xie, Y.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Xiong, F.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 8 ] [Du, Z.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 9 ] [Li, L.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 10 ] [Deng, J.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 11 ] [Xu, C.]Key Laboratory of Optoelectronics Technology, Beijing University of Technology, Beijing, 100124, China

Reprint 's Address:

  • [Sun, J.]National and Local United Engineering Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou UniversityChina

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Source :

Materials

ISSN: 1996-1944

Year: 2020

Issue: 9

Volume: 13

3 . 6 2 3

JCR@2020

3 . 1 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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