Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides - Details

author：

Wei, R. (Wei, R..) ^[1] | Ge, L. (Ge, L..) ^[2] | Bao, H. (Bao, H..) ^[3] | Liao, S. (Liao, S..) ^[4] | Li, Y. (Li, Y..) ^[5]

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Abstract：

An　efficient　copper-catalyzed　synthesis　of　carbamoyl　azides　directly　from　aldehydes　has　been　developed.　Both　aromatic　aldehydes　and　aliphatic　aldehydes,　together　with　other　commercially　available　reactants,　can　be　used　as　substrates　in　this　radical　relay　reaction.　Broad　substrate　scope,　simple　operation,　readily　available　reagents,　and　good　functionality　tolerance　make　this　method　very　attractive.　©　2019　Georg　Thieme　Verlag.　All　rights　reserved.

Keyword：

aliphatic aldehydes; aromatic aldehydes; carbamoyl azides; copper catalyst; nitrogenation; radical

Community：

[ 1 ] [Wei, R.]College of Chemistry, Fuzhou University, 2 Xueyuan Road, Fuzhou, Fujian, 350108, China
[ 2 ] [Wei, R.]State Key Laboratory of Structural Chemistry, Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China
[ 3 ] [Ge, L.]State Key Laboratory of Structural Chemistry, Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China
[ 4 ] [Bao, H.]State Key Laboratory of Structural Chemistry, Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China
[ 5 ] [Liao, S.]College of Chemistry, Fuzhou University, 2 Xueyuan Road, Fuzhou, Fujian, 350108, China
[ 6 ] [Li, Y.]State Key Laboratory of Structural Chemistry, Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China

Reprint 's Address：

[Liao, S.]College of Chemistry, Fuzhou University, 2 Xueyuan Road, China

Email：

shliao@fzu.edu.cn

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Source ：

Synthesis (Germany)

ISSN： 0039-7881

Year： 2019

Issue： 24

Volume： 51

Page： 4645-4649

2 . 6 7 5

JCR@2019

2 . 2 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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