A Series of Unprecedented Linear Mixed-Metal-Substituted Polyoxometalate Trimers: Syntheses, Structures, Luminescence, and Proton Conductivity Properties - Details

author：

Li, Z. (Li, Z..) ^[1] | Lin, L.-D. (Lin, L.-D..) ^[2] | Zhao, D. (Zhao, D..) ^[3] | Sun, Y.-Q. (Sun, Y.-Q..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

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Abstract：

In　this　paper,　we　report　a　series　of　novel　mixed-metal-substituted　organic-inorganic　hybrid　polyoxometalates　(POMs)　H3[(CH3)4N]14[NaLn(PW11O39)3]·18H2O　(1-Ln,　Ln　=　Nd,　Sm,　Eu)　via　one-pot　solvothermal　synthesis　methods,　which　present　the　first　series　of　polyoxometalate　trimers　composed　of　both　alkali-metal-　and　lanthanide-substituted　keggin-type　POMs.　The　trimeric　heterometallic　polyoxoanions　in　1-Ln　show　an　interesting　linear　arrangement　and　can　be　further　packed　together　to　generate　a　packing　structure　with　cations　[(CH3)4N]+　and　H3O+　filling　the　gaps　between　polyoxoanions.　Compounds　1-Ln　are　characterized　by　single-crystal　X-ray　diffraction　analysis,　TGA,　IR　and　PXRD.　Additionally,　the　luminescence　and　proton　conductive　properties　of　1-Ln　are　also　characterized.　©　2019　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

Heterometallic compounds; Luminescence; Polyoxometalates; Proton conductivity

Community：

[ 1 ] [Li, Z.]State Key Laboratory of Photocatalysis on Energy an Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 2 ] [Lin, L.-D.]State Key Laboratory of Photocatalysis on Energy an Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 3 ] [Zhao, D.]Department of Chemistry, College of Chemistry, Fuqing Branch of Fujian Normal University, Fujian, 350300, China
[ 4 ] [Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy an Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 5 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy an Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China

Reprint 's Address：

[Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy an Environment, College of Chemistry, Fuzhou UniversityChina

Email：

sunyq@fzu.edu.cn

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Source ：

European Journal of Inorganic Chemistry

ISSN： 1434-1948

Year： 2019

Issue： 3

Volume： 2019

Page： 437-441

2 . 5 2 9

JCR@2019

2 . 2 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 20

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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