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author:

Shen, H. (Shen, H..) [1] | Wang, Y. (Wang, Y..) [2] | Zhu, Z. (Zhu, Z..) [3] | Li, J. (Li, J..) [4] | You, Z. (You, Z..) [5] | Tu, C. (Tu, C..) [6]

Indexed by:

Scopus

Abstract:

Intense 2.9 µm emission corresponding to Dy3+:6H13/2 → 6H15/2 transition was achieved in Yb3+/Dy3+ codoped CaYAlO4 crystal for the first time. The effects of Yb3+ on the spectroscopic properties and energy transfer mechanisms were investigated. In comparison with Dy3+ singly-doped CaYAlO4 crystal, Yb3+/Dy3+ codoped crystal not only has intense 2.9 µm emission, but also has longer upper laser level lifetime, which facilitates particle number inversion and laser behavior in 2.9 µm. Furthermore, the energy transfer efficiency from Yb3+ to Dy3+ in Yb3+/Dy3+ codoped crystal was as high as 87.3%, indicating effective energy transfer of Yb3+. Besides, the energy transfer microscopic parameters between Yb3+ and Dy3+ were theoretically analyzed. The results indicate that the introduction of Yb3+ is very beneficial for achieving 2.9 µm laser in Dy3+: CaYAlO4 crystal, which could act as a potential gain media for LD pumped mid-infrared laser. © 2018 Elsevier B.V.

Keyword:

Crystal growth; Energy transfer microscopic parameters; Mid-infrared laser; Spectroscopic properties

Community:

  • [ 1 ] [Shen, H.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
  • [ 2 ] [Shen, H.]College of Chemistry, Fuzhou University, Fuzhou City, Fujian Province 350116, China
  • [ 3 ] [Wang, Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
  • [ 4 ] [Zhu, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
  • [ 5 ] [Li, J.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
  • [ 6 ] [You, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
  • [ 7 ] [Tu, C.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China

Reprint 's Address:

  • [Tu, C.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

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Source :

Journal of Luminescence

ISSN: 0022-2313

Year: 2019

Volume: 208

Page: 188-192

3 . 2 8

JCR@2019

3 . 3 0 0

JCR@2023

ESI HC Threshold:138

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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