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author:

Li, Z. (Li, Z..) [1] | Rao, F. (Rao, F..) [2] | Song, S. (Song, S..) [3] | Uribe-Salas, A. (Uribe-Salas, A..) [4] | López-Valdivieso, A. (López-Valdivieso, A..) [5]

Indexed by:

Scopus

Abstract:

Effects of common ions, namely hydroxyl ions and carbonate, on the adsorption and flotation of malachite with salicylaldoxime as a collector was investigated, making use of solubility, micro-flotation, zeta potential, contact angle, FTIR, and XPS measurements. The results suggested that hydroxyl and carbonate ions affect malachite recovery through altering solubility of this mineral. Under conditions of lower solubility, more stable copper atoms acted as adsorption sites for retaining salicylaldoxime on the malachite surface, and the collector consumed by copper species in slurry was reduced. This allowed more collectors to get adsorbed onto malachite surface, resulting in improved malachite recovery. Zeta potential, FTIR, and XPS measurements indicated that salicylaldoxime chemically adsorbs onto malachite by forming copper salicylaldoxime chelates, in which two salicylaldoxime molecules react with one copper atom by N atom and the O atom combined with benzene ring. © 2019 Elsevier B.V.

Keyword:

Carbonate; Hydroxyl; Malachite flotation; Salicylaldoxime; Solubility

Community:

  • [ 1 ] [Li, Z.]School of Zijin Mining, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 2 ] [Li, Z.]CONACYT Instituto de Investigación en Metalurgia y Materiales, Universidad Michoacana de San Nicolás de Hidalgo, Morelia, Mich. 58030, Mexico
  • [ 3 ] [Li, Z.]School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan, Hubei 430070, China
  • [ 4 ] [Rao, F.]School of Zijin Mining, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 5 ] [Rao, F.]CONACYT Instituto de Investigación en Metalurgia y Materiales, Universidad Michoacana de San Nicolás de Hidalgo, Morelia, Mich. 58030, Mexico
  • [ 6 ] [Song, S.]School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan, Hubei 430070, China
  • [ 7 ] [Song, S.]Instituto de Metalurgia, Universidad Autónoma de San Luís Potosí, San Luis Potosí, S.L.P. 78210, Mexico
  • [ 8 ] [Uribe-Salas, A.]CINVESTAV-IPN, Unidad Saltillo, Saltillo, Coah. 25900, Mexico
  • [ 9 ] [López-Valdivieso, A.]Instituto de Metalurgia, Universidad Autónoma de San Luís Potosí, San Luis Potosí, S.L.P. 78210, Mexico

Reprint 's Address:

  • [Rao, F.]School of Zijin Mining, Fuzhou UniversityChina

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Source :

Colloids and Surfaces A: Physicochemical and Engineering Aspects

ISSN: 0927-7757

Year: 2019

Volume: 577

Page: 421-428

3 . 9 9

JCR@2019

4 . 9 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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