Direct Synthesis of Hierarchical FeCu-ZSM-5 Zeolite with Wide Temperature Window in Selective Catalytic Reduction of NO by NH3 - Details

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Abstract：

In　this　article,　we　report　a　one-pot　synthesis　strategy　to　directly　synthesize　the　hierarchical　FeCu-ZSM-5　zeolite.　Its　physicochemical　properties　were　studied　by　various　characterization　techniques　and　catalytic　performance　was　tested　in　selective　catalytic　reduction　(SCR)　of　NO　with　NH3　as　reductant.　The　characterization　results　show　that:　compared　with　three　reference　zeolites　Fe/ZSM-5,　Cu/ZSM-5,　and　Fe/Cu/ZSM-5　prepared　through　an　incipient　wetness　impregnation　method,　the　synthesized　FeCu-ZSM-5　zeolite　exhibits　hierarchical　micro-mesoporous　structures,　more　Fe3+　in　zeolite　framework,　and　larger　isolated　Cu2+　species.　Therefore,　when　used　as　a　catalyst　in　NH3-SCR,　the　resulting　hierarchical　FeCu-ZSM-5　catalyst　shows　better　catalytic　performance　(high　NO　conversion　and　N2　selectivity)　in　a　wide　temperature　window　and　higher　hydrothermal　stability　than　the　three　reference　catalysts.　Our　work　provides　a　simple　and　facile　route　to　prepare　the　promising　NH3-SCR　catalyst　for　practical　applications　in　controlling　NOx　emissions.　©　2019　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

direct synthesis; FeCu-ZSM-5 zeolite; hierarchical pore structure; selective catalytic reduction

Community：

[ 1 ] [Yue, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 2 ] [Liu, B.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 3 ] [Lv, N.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 4 ] [Wang, T.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 5 ] [Bi, X.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 6 ] [Bi, X.]Department of Chemical & Biological Engineering, University of British Columbia, Vancouver, BC V6T 1Z3, Canada
[ 7 ] [Zhu, H.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 8 ] [Yuan, P.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 9 ] [Bai, Z.]State Key Laboratory of Photocatalysis on Energy & Environment College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 10 ] [Cui, Q.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 11 ] [Bao, X.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
[ 12 ] [Bao, X.]State Key Laboratory of Photocatalysis on Energy & Environment College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

[Bao, X.]National Engineering Research Center of Chemical Fertilizer Catalyst College of Chemical Engineering, Fuzhou UniversityChina

Email：

baoxj@fzu.edu.cn

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Source ：

ChemCatChem

ISSN： 1867-3880

Year： 2019

Issue： 19

Volume： 11

Page： 4744-4754

4 . 8 5 3

JCR@2019

3 . 8 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 31

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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