Synthesis of a 6-nm-Long Transition-Metal-Rare-Earth-Containing Polyoxometalate - Details

author：

Han, Q. (Han, Q..) ^[1] | Li, Z. (Li, Z..) ^[2] | Liang, X. (Liang, X..) ^[3] | Ding, Y. (Ding, Y..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

Indexed by：

Scopus

Abstract：

An　extremely　long　ribbon-shaped　polyoxometalate　(POM)　octamer,　{Eu16Co7Se16W128O448(CIT)10(HCIT)2(NO3)4(OH)4(H2O)52}　(H4CIT　=　citric　acid),　with　a　maximum　length　of　ca.　6　nm　has　been　obtained,　which　is　the　longest　molecular　POM　reported　to　date　and　the　first　Dawson-based　3d-4f-containing　selenotungstate(IV).　The　nanoscale　octamer　is　built　from　8　new　Dawson-type　Eu2W2-substituted　selenotungstates　{(Eu2W2O4)Se2W14O52}　bridged　by　12　H4CIT　ligands　and　3　Co2+　ions,　giving　rise　to　a　rare　giant　inorganic-organic　hybrid　molecular　POM　with　more　than　150　metal　centers　(7　CoII,　16　EuIII,　16　SeIV,　and　128　WVI).　Especially,　with　128　W　centers　and　more　than　800　non-H　atoms,　the　POM　octamer　also　represents　the　largest　known　3d-4f-containing　polyoxotungstate.　Copyright　©　2019　American　Chemical　Society.

Keyword：

Community：

[ 1 ] [Han, Q.]State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China
[ 2 ] [Li, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 3 ] [Liang, X.]State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China
[ 4 ] [Ding, Y.]State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China
[ 5 ] [Ding, Y.]State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China
[ 6 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, 350108, China

Reprint 's Address：

[Ding, Y.]State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou UniversityChina

Email：

dingyong1@lzu.edu.cn

Show more details

Related Keywords：

Source ：

Inorganic Chemistry

ISSN： 0020-1669

Year： 2019

Issue： 19

Volume： 58

Page： 12534-12537

4 . 8 2 5

JCR@2019

4 . 3 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to