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author:

Li, Z. (Li, Z..) [1] | Liu, X. (Liu, X..) [2] | Guo, K. (Guo, K..) [3] | Wang, H. (Wang, H..) [4] | Cai, B. (Cai, B..) [5] | Chang, F. (Chang, F..) [6] | Hong, C. (Hong, C..) [7] | Dai, P. (Dai, P..) [8]

Indexed by:

Scopus

Abstract:

The FeCoCrNiAl high-entropy alloys (HEA) was used as binder of the Ti(C, N)–TiB2 composite cermets. The Ti(C, N)–TiB2–FeCoCrNiAl HEA composite cermets were successfully fabricated by mechanical alloying (MA) and vacuum hot-pressing sintering (VHPS) at different sintering temperatures. The microstructure, room-temperature hardness, fracture toughness, bending strength, high-temperature hardness and oxidation behavior were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Vickers hardness testing, indentation method, three point bending method, high-temperature vacuum hardness testing and cyclic oxidation. For the Ti(C, N)–TiB2-HEA composite cermets, apart from Ti(C, N) and TiB2 phases, also a minority Fe2B were detected in the XRD patterns. TEM observation revealed that the structure of the HEA binder was a solid solution where the Ti(C, N) and TiB2 were tightly bound. The Ti(C, N)–TiB2 composite cermets with a Ni/Co binder was selected as a reference. The experimental results indicated that the composite cermets with the HEA binder possesses excellent oxidation resistance. This is attributed to the formation of a continuous and dense external oxide scale and TiO2 layer that effectively impede inward oxygen transport, which leads to a remarkable improvement in the oxidation resistance. The Ti(C, N)–TiB2-HEA composite cermets sintered at 1500 °C showed excellent fracture toughness of 7.9 ± 0.1 MPa.m1/2. And the Ti(C, N)–TiB2-HEA composite cermets sintered at 1550 °C showed excellent hardness and bending strength of 1977.3 ± 20 HV10 and 768.6 ± 20 MPa, respectively. The high-temperature hardness of the HEA binder composite cermets was 993.7 ± 30 HV20, which was superior to the Ni/Co binder value of 668.1 ± 30 HV20 at 1000 °C. © 2019 Elsevier B.V.

Keyword:

FeCoCrNiAl high-entropy alloys; High-temperature properties; Microstructure; Room-temperature properties; Ti(C, N)–TiB2-HEA composite cermets

Community:

  • [ 1 ] [Li, Z.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 2 ] [Li, Z.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 3 ] [Liu, X.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 4 ] [Liu, X.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 5 ] [Guo, K.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Wang, H.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Cai, B.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 8 ] [Cai, B.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 9 ] [Chang, F.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 10 ] [Chang, F.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 11 ] [Hong, C.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 12 ] [Hong, C.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 13 ] [Dai, P.]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, 350118, China
  • [ 14 ] [Dai, P.]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou, 350108, China
  • [ 15 ] [Dai, P.]School of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Dai, P.]College of Materials Science and Engineering, Fujian University of TechnologyChina

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Source :

Materials Science and Engineering A

ISSN: 0921-5093

Year: 2019

Volume: 767

4 . 6 5 2

JCR@2019

6 . 1 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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