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author:

Jin, Y. (Jin, Y..) [1] | Long, J. (Long, J..) [2] | Ma, X. (Ma, X..) [3] | Zhou, T. (Zhou, T..) [4] | Zhang, Z. (Zhang, Z..) [5] | Lin, H. (Lin, H..) [6] | Wang, X. (Wang, X..) [8]

Indexed by:

Scopus

Abstract:

The grain size and surface oxygen vacancy concentration of ZnO have great influence on its photocatalytic performance. In this work, caged Iodine-modified ZnO (I-ZnO-n) catalyst with nano-structure and surface oxygen vacancy were successfully prepared by reflux method. The crystal structure, surface properties and optical properties were characterized by XRD, SEM, TEM, RAMAN, ESR and EPR. And the photocatalytic antibacterial activity under visible light has been tested. The results show that the nano-structure I-ZnO-n's band gap is narrow than ZnO because of the existence of oxygen vacancy. And I-ZnO-n exhibits better antibacterial property than micron-structured Iodine-modified ZnO. The ESR and electrochemical experiments confirm that the I-ZnO-n has much more surface oxygen vacancy and higher separation efficiency of photogenic carriers than micron-structured Iodine-modified ZnO, which results its superior photocatalytic performance. © 2019 Elsevier B.V.

Keyword:

Disinfection; Iodine-modified ZnO; Photocatalysis; Surface oxygen vacancy defects

Community:

  • [ 1 ] [Jin, Y.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Long, J.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Ma, X.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zhou, T.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Zhang, Z.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Lin, H.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Long, J.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Wang, X.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Lin, H.]College of chemistry of Fuzhou University, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou UniversityChina

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2019

Volume: 256

1 6 . 6 8 3

JCR@2019

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 95

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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