Perfluorocarboxylic Anhydrides Triggered Cyclization: Access to 4-Perfluoroalkylpyridines - Details

author：

Wang, Z. (Wang, Z..) ^[1] | You, C. (You, C..) ^[2] | Wang, C. (Wang, C..) ^[3] | Weng, Z. (Weng, Z..) ^[4]

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Abstract：

A　double　nucleophilic　addition-cyclization-elimination　cascade　is　developed,　that　allows　various　2,6-diaryl-4-perfluoroalkylpyridines　to　be　synthesized　in　one　step　from　easily　available　enamides　and　perfluorocarboxylic　anhydrides.　The　procedure　is　also　operationally　simple　and　scalable　and　provides　access　to　the　facial　construction　of　4-fluoroalkylpyridines,　which　are　of　great　interest　in　medicinal　chemistry.　Copyright　©　2019　American　Chemical　Society.

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[ 1 ] [Wang, Z.]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 2 ] [You, C.]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian, 350108, China
[ 3 ] [Wang, C.]Institute of Plant Protection, Fujian Academy of Agricultural Sciences, Fuzhou, 350013, China
[ 4 ] [Weng, Z.]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian, 350108, China

Reprint 's Address：

[Wang, C.]Institute of Plant Protection, Fujian Academy of Agricultural SciencesChina

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295075872@qq.com

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2019

Issue： 22

Volume： 84

Page： 14926-14935

4 . 3 3 5

JCR@2019

3 . 4 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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