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author:

Zhang, Y. (Zhang, Y..) [1] | Cai, J. (Cai, J..) [2] | Liu, Y. (Liu, Y..) [3] | Wang, X. (Wang, X..) [4] | Au, C.-T. (Au, C.-T..) [5] | Jiang, L. (Jiang, L..) [6]

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Scopus

Abstract:

A novel strategy for the synthesis of sintering-resistant Pt/Ce-Ti-T catalyst with high activity and stability for water-gas shift (WGS) reaction is demonstrated. By adding dopamine followed by thermal treatment under an inert atmosphere, the Pt/Ce-Ti-T catalyst was obtained after the removal of sacrificial dopamine through oxidation. For a Pt/Ce-Ti catalyst subjected to ageing but without the participation of dopamine, it showed a sharp decrease of CO conversion from ca. 90% to 48% at 400 °C within 12 h, while the similarly aged Pt/Ce-Ti-T catalyst displays a CO conversion of ca. 82% and no obvious sign of deactivation. It was found that in the case of Pt/Ce-Ti, there was increase of Pt nanoparticle size from 7.25 to 20.72 nm, while there was no significant increase in the Pt/Ce-Ti-T case (from 7.80 to 8.55 nm). The observation can be associated with the strengthening of metal-support contact as a result of dopamine mediation. The outcome is enhanced interfacial bonding between Pt nanoparticles and the Ce-Ti support, making the Pt/Ce-Ti-T catalyst highly resistant to sintering and has commendable durability for WGS reaction. © 2019

Keyword:

Dopamine mediation; Platinum nanoparticles; Strong metal-support interaction; Thermal stability; Water-gas shift reaction

Community:

  • [ 1 ] [Zhang, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Cai, J.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 3 ] [Liu, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 4 ] [Wang, X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 5 ] [Au, C.-T.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 6 ] [Jiang, L.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address:

  • [Wang, X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou UniversityChina

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Source :

Applied Surface Science

ISSN: 0169-4332

Year: 2019

Volume: 496

6 . 1 8 2

JCR@2019

6 . 3 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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