Sustainable Radical Cascades to Synthesize Difluoroalkylated Pyrrolo[1,2-a]indoles - Details

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Abstract：

We　disclose　herein　a　photocatalytic　difluoroalkylation　and　cyclization　cascade　reaction　of　N-(but-2-enoyl)indoles　with　broad　substrate　scopes　in　up　to　90%　isolated　yield.　This　method　provides　sustainable　and　efficient　access　to　synthesize　difluoroalkylated　pyrrolo[1,2-a]indoles　with　a　quaternary　carbon　center　under　mild　conditions.　©　2018　American　Chemical　Society.

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[ 1 ] [Huang, H.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Yu, M.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 3 ] [Su, X.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Guo, P.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Zhao, J.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 6 ] [Zhou, J.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 7 ] [Li, Y.]Department of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 8 ] [Li, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

[Li, Y.]Department of Chemistry, Fuzhou UniversityChina

Email：

liyi-chem@fzu.edu.cn

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2018

Issue： 4

Volume： 83

Page： 2425-2437

4 . 7 4 5

JCR@2018

3 . 4 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 49

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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