[CH 3 NH 3 ] 4 Ga 4 SbS 9 S 0.28 O 0.72 H: A Three-Dimensionally Open-Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni 2+ Ion-Exchange Property - Details

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Abstract：

An　open-framework　chalcogenidoantimonate,　namely,　[CH　3　NH　3　]　4　Ga　4　SbS　9　S　0.28　O　0.72　H　(1),　has　been　solvothermally　synthesized　and　structurally　characterized.　Interestingly,　1　showed　Ni　2+　ion-exchange　properties　and　wide　pH　resistance,　with　a　maximum　exchange　capacity　of　76.9　mg　g　−1　.　To　the　best　of　our　knowledge,　this　is　the　first　example　of　amine-directed　three-dimensional　(3D)　heterometallic　chalcogenidometalates　for　highly　selective　Ni　2+　ion　capture　with　a　high　distribution　coefficient　(K　d　=1.65×10　5　mL　g　−1　).　©　2018　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

adsorbents; heterometallic chalcogenidoantimonate; high selectivity; Ni 2+ ion-exchange; solvothermal synthesis

Community：

[ 1 ] [Zhang, B.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
[ 2 ] [Zhang, B.]College of Chemistry and Chemical Engineering, Liaocheng University, Shandong, Liaocheng, 252059, China
[ 3 ] [Li, W.-A.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
[ 4 ] [Li, W.-A.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
[ 5 ] [Liao, Y.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
[ 6 ] [Zhang, C.]College of Chemistry and Chemical Engineering, Liaocheng University, Shandong, Liaocheng, 252059, China
[ 7 ] [Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
[ 8 ] [Huang, X.-Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

Reprint 's Address：

[Feng, M.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

fml@fjirsm.ac.cn

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Source ：

Chemistry - An Asian Journal

ISSN： 1861-4728

Year： 2018

Issue： 6

Volume： 13

Page： 672-678

3 . 6 9 8

JCR@2018

3 . 5 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：2

CAS Journal Grade：3

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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