Enantioselective Conjugate Addition of 2-Acylimidazoles with Nitroalkenes Promoted by Chiral-at-Metal Rhodium(III) Complexes - Details

author：

Thota, G.K. (Thota, G.K..) ^[1] | Sun, G.-J. (Sun, G.-J..) ^[2] | Deng, T. (Deng, T..) ^[3] | Li, Y. (Li, Y..) ^[4] | Kang, Q. (Kang, Q..) ^[5]

Indexed by：

Scopus

Abstract：

An　enantioselective　conjugate　addition　of　2-acylimidazoles　with　nitroalkenes　catalyzed　by　chiral-at-metal　rhodium(III)　complex　under　mild　reaction　conditions　was　developed,　affording　versatile　γ-nitro　ketone　skeletons　in　good　yields　with　excellent　enantioselectivities　(up　to　＞99%　ee).　(Figure　presented.).　©　2018　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

Chiral-at-metal Complex; Conjugate addition; Enantioselective; Rhodium catalysis

Community：

[ 1 ] [Thota, G.K.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 2 ] [Sun, G.-J.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 3 ] [Deng, T.]Department of Chemistry, Fuzhou University350116, China
[ 4 ] [Li, Y.]Department of Chemistry, Fuzhou University350116, China
[ 5 ] [Kang, Q.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China

Reprint 's Address：

[Kang, Q.]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, China

Email：

kangq@fjirsm.ac.cn

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Source ：

Advanced Synthesis and Catalysis

ISSN： 1615-4150

Year： 2018

Issue： 6

Volume： 360

Page： 1094-1098

5 . 4 5 1

JCR@2018

4 . 4 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 12

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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