The formation and crystal structure of dihydronitidine and discussion of anticancer mechanism of nitidine cation - Details

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Abstract：

The　paper　reports　the　formation　and　crystal　structure　of　dihydronitidine,　expounds　the　reasons　and　conditions　of　easily　formed　oxynitidine,　and　discusses　anticancer　mechanism　of　nitidine　(cation).　The　crystallographic　parameters　of　dihydronitidine　are:　space　group　P2　1　n　,　a　=　12.54(1),　b　=　9.148(5),　c　=　14.748(8)A　̊,　β　=　92.12(6)　°,　Z　=　4.　4108　independent　reflections　were　collected　within　the　range　of　3　°≤2θ≤54　°,　of　which　2137　intensity　data　with　I≤3σ(I)　were　used　in　the　structural　determination.　The　crystal　structure　has　been　refined　by　full　matrix　least-square　method　to　a　final　R　of　0.050.　©　1992.

Keyword：

alkaloid; anticancer; crystal structure

Community：

[ 1 ] [Chen, Y.-z.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China
[ 2 ] [Tang, G.-y.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China
[ 3 ] [Xu, B.-j.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China
[ 4 ] [Wu, Q.-j.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China
[ 5 ] [Lu, C.-z.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China
[ 6 ] [Li, J.-q.]Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 7 ] [Huang, Z.-x.]Department of Chemistry, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address：

[Chen, Y.-z.]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, 350002, China

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SCIENCE IN CHINA SERIES B-CHEMISTRY

ISSN： 1001-652X

Year： 1992

Issue： 9

Volume： 35

Page： 1101-1109

1 . 1 9 9

JCR@2011

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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