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author:

Zheng, X. (Zheng, X..) [1] | Fu, W. (Fu, W..) [2] | Yu, Y. (Yu, Y..) [3] | Lin, J. (Lin, J..) [4] | Wei, K. (Wei, K..) [5]

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Scopus CSCD

Abstract:

A commercial activated carbon was treated in nitrogen flow using a microwave device as heat source. The effect of microwave treatment of activated carbon on its composition, structure and texture, as well as ruthenium dispersion on it was studied. The microwave treatment of activated carbon could eliminate carbon impurities, improved the stability of activated carbon support under the ammonia synthesis condition, at the same time, the surface area and porosity of activated carbon did not decrease. With the microwave-treated carbon as the support, the Ru catalysts had higher Ru dispersion, and can protect the ruthenium particles from sintering, when the catalysts were reduced at higher temperature. The activity and stability of the carbon-supported Ru catalysts were greatly improved with microwave-treated carbon as the support. With CW5 as the support, the ammonia concentration in the effluent for 4% Ru-Ba-Cs/CW5 catalyst was 16 .78%, after undergoing the above conditions, the catalyst activity would be unchanged.

Keyword:

Activated carbon; Ammonia synthesis; Barium; Cesium; Microwave treatment; Promoter; Ruthenium; Supported catalyst

Community:

  • [ 1 ] [Zheng, X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China
  • [ 2 ] [Fu, W.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China
  • [ 3 ] [Yu, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China
  • [ 4 ] [Lin, J.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China
  • [ 5 ] [Wei, K.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China

Reprint 's Address:

  • [Zheng, X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China

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Source :

Chinese Journal of Catalysis

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2002

Issue: 6

Volume: 23

Page: 565-566

1 5 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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