Home>Results

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

[期刊论文]

Synthesis and characterization of a cadmium chloride complex with an N5O3 cryptand

Share
Edit Delete 报错

author:

Ma, Z. (Ma, Z..) [1] | Liu, S.-X. (Liu, S.-X..) [2]

Indexed by:

Scopus

Abstract:

A complex of cadmium chloride with an N5O3 cryptand L (1,4,13,16,27-pentaaza-6,9:18,21:29,32-tribenzo-10,22,33-trioxa- bicyclopentatriacontane), [CdL(H2O)][CdCl4]·0.5H2O (1), was synthesized and characterized by X-ray diffraction and NMR studies. The colourless crystals are orthorhombic, space group Pna21 with a=25.2257(4), b=16.5098(3), c=9.9615(1) Å, Z=4, Dc=1.526 g cm-3 and R=0.0312. The Cadmium atoms in [CdL(H2O)]2+ and in [CdCl4]2- have trigonal bipyramidal and tetrahedral coordination spheres, respectively. The conformation of the ligand in the title compound is endo-endo and the distance between the two bridgehead nitrogen atoms in L is 10.023(7) Å.

Keyword:

Cadmium complex; Cryptand; Crystal structure; Macrobicyclic compound

Community:

  • [ 1 ] [Ma, Z.]Central Laboratory, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Liu, S.-X.]Stt. Key Lab. of Struct. Chemistry, Fujian Inst. Res. Struct. Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address:

  • [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou, 350002, China

Show more details

Source :

Journal of Coordination Chemistry

ISSN: 0095-8972

Year: 2003

Issue: 8

Volume: 56

Page: 655-659

0 . 8 4 1

JCR@2003

2 . 2 0 0

JCR@2023

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

30 Days PV: 0

Affiliated Colleges:

Online/Total:48/10134863
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1