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[期刊论文]

Effect of Sr2+ on properties of Li0.2375+xLa0.5875-x SrxTiO3-LaPO4 system

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author:

Liu, H. (Liu, H..) [1] | Wang, W. (Wang, W..) [2] | Li, R. (Li, R..) [3] | Unfold

Indexed by:

Scopus

Abstract:

Li0.2375+xLa0.5875-x SrxTiO3-LaPO4 fast ionic conductor was synthesized by high temperature solid state reaction. A. C. impedance measurements show that the system has higher conductivity in low doping content of Sr2+, but the conductivity goes down from 5.78×10-5 to 3.11×10-7 S·cm-1 with increasing the content of Sr2+. The activation energy is about 20 kJ·mol-1 in the temperature range of 25-400°C. X-ray powder diffraction shows that the doping Sr2+ would not affect the structure of compositions in the system. The main phase is Li0.2375+xLa0.5875-x SrxTiO3 perovskite solid solution, LaPO4 as a second phase can also be found. With increasing the content of Sr2+ (x>0.05), another phase SrTiO3 appears. IR measurement also indicates that the structure of compositions in the system would not be affected by Sr2+ doping. The decomposition voltage of Li0.2375+xLa0.5875-x SrxTiO3-LaPO4 remain unchanged (1.5 V).

Keyword:

Fast ionic conductor; Inorganic chemistry; Perovskite; Rare earths; Sr2+ doping

Community:

  • [ 1 ] [Liu, H.]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 2 ] [Wang, W.]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 3 ] [Li, R.]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 4 ] [Cai, Z.]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China

Reprint 's Address:

  • [Liu, H.]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China

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Source :

Journal of Rare Earths

ISSN: 1002-0721

Year: 2004

Issue: 2

Volume: 22

Page: 223-226

0 . 4 9 3

JCR@2004

5 . 2 0 0

JCR@2023

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

30 Days PV: 2

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