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Abstract:
Li0.2375+xLa0.5875-x SrxTiO3-LaPO4 fast ionic conductor was synthesized by high temperature solid state reaction. A. C. impedance measurements show that the system has higher conductivity in low doping content of Sr2+, but the conductivity goes down from 5.78×10-5 to 3.11×10-7 S·cm-1 with increasing the content of Sr2+. The activation energy is about 20 kJ·mol-1 in the temperature range of 25-400°C. X-ray powder diffraction shows that the doping Sr2+ would not affect the structure of compositions in the system. The main phase is Li0.2375+xLa0.5875-x SrxTiO3 perovskite solid solution, LaPO4 as a second phase can also be found. With increasing the content of Sr2+ (x>0.05), another phase SrTiO3 appears. IR measurement also indicates that the structure of compositions in the system would not be affected by Sr2+ doping. The decomposition voltage of Li0.2375+xLa0.5875-x SrxTiO3-LaPO4 remain unchanged (1.5 V).
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Journal of Rare Earths
ISSN: 1002-0721
Year: 2004
Issue: 2
Volume: 22
Page: 223-226
0 . 4 9 3
JCR@2004
5 . 2 0 0
JCR@2023
JCR Journal Grade:3
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