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[期刊论文]

Synthesis and crystal structure of Ni(II) complex with N-salicylaldehyde- N′-phenoxyacetylhydrazine ligand

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author:

Chen, X.-H. (Chen, X.-H..) [1] | Liu, S.-X. (Liu, S.-X..) [2]

Indexed by:

Scopus PKU CSCD

Abstract:

The title complex NiL(py)3, where H2L = N-salicylaldehyde-N′-phenoxyacetyl hydrazine, was prepared and characterized by X-ray diffraction. The single crystal of the title compound, Ni(C15H12N2O3)(C5H 5N)3, is of monoclinic, space group P21/c with a = 11.900(1), b = 9.6855(7), c = 23.658(2) Å, β = 92.357(2)°, V = 2724.5(4) Å3, Z = 4, F(000) = 1176, Dc = 1.376 g/cm3, μ = 0.753 mm-1, R = 0.0332 and wR = 0.0820. The coordination polyhedron around the nickel atom is an elongated octahedron. The basal plane consists of one phenol oxygen, one amine carbonyl oxygen and one hydrazine nitrogen atoms from the ligand L and one nitrogen atom from one coordinated pyridine ligand, while the axial sites are occupied by two nitrogen atoms of two coordinated pyridine ligands.

Keyword:

Crystal structure; Hydrazone; Nickel complex; Schiff base

Community:

  • [ 1 ] [Chen, X.-H.]Central Laboratory, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Liu, S.-X.]State Key Lab. of Struct. Chemistry, Fujian Inst. Res. Struct. of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Reprint 's Address:

  • 刘世雄

    [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou 350002, China

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2004

Issue: 1

Volume: 23

Page: 33-37

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

30 Days PV: 0

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