A novel vanadyl selenite templated by organic salt: [(VO)(H 2O) 2(SeO 3)] 2[(H 2pipe) SO 4] - Details

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Abstract：

The　title　compound　[(VO)(H　2O)　2(SeO　3)]　2[(H　2pipe)SO　4]　was　synthesized　under　hydrothermal　condition　with　VOSO　4,　piperazidine　(pipe),　and　SeO　2,　and　its　crystal　structure　was　established　using　single-crystal　X-ray　diffraction　method.　The　title　compound　was　characterized　with　IR□Fluorescence.　The　crystal　data:　P-1　(No.　2),　a　=　8.633(2)　Å,　b=　9.223(2)　Å,　c=　12.508(3)　Å,　α　=109.28(3)°,　β　=90.42(3)°,　γ　=　107.79(3)°,　Mr　=　644.08,　V=888.5(3)　Å　3,　Z=2,　Dc　=　2.407　g　cm　-3,　μ　=5.350　mm　-1,　F(000)=632.　The　structure　of　the　title　compound　consists　of　an　infinite　neutral　ladder　chain,　which　is　built　up　from　VO　6　octahedral　and　SeO　3　pyramidal　units　sharing　vertices,　and　organic　salt.　The　biprotonized　pipe　(piperazidine)　and　SO　4　2-　interact　with　one　another　and　the　inorganic　chain　through　strong　hydrogen　bonds　N-H···O　or　O-H···O　to　give　a　3D　structure.　Hydrogen　bonds　play　a　role　of　stabilization　structure.

Keyword：

Crystal structure; hydrogen bonding; hydrothermal synthesis; organic-inorganic hybrid vanadyl selenite

Community：

[ 1 ] [Lian, Z.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China
[ 2 ] [Huang, C.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China
[ 3 ] [Zhang, H.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China
[ 4 ] [Yang, H.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China
[ 5 ] [Zhang, Y.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China
[ 6 ] [Yang, X.]Dept. Chem. Key Lab. Solid State C., Fuzhou University, Fuzhou, Fujian, 350002, People's R., China

Reprint 's Address：

Email：

cchuang@fzu.edu.cn

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Source ：

Journal of Chemical Crystallography

ISSN： 1074-1542

Year： 2004

Issue： 8

Volume： 34

Page： 489-494

0 . 5 1 2

JCR@2004

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JCR@2023

JCR Journal Grade：4

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