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Highly transparent, flexible, low percolation threshold and conductive nanocomposite membranes were prepared by mixing poly (aniline -co - sulfonic aniline) (PANS A) nanoparticle suspension (average 58 nm in diameter) with cellulose diacetate solution under ultrasonic wave for 2.0 h, and then by casting the solution onto glass plate. PANS A nanoparticles were synthesized by oxidative copolymerization of aniline and 2 - methoxyaniline - 5 - sulfonic acid in 1.0 mol/L HC1 aqueous solution with ammonium peroxydisulfate as oxidant without emulsifier or stabilizer. The nanocomposite membranes show very low percolation threshold. When PANS A volume fraction in mixture is 0.08%, transparency, tensile strength and conductivity of the nanocomposite membrane can reach 83% - 89%, 98% and 108 times respectively of cellulose diacetate homogeneous membrane. With increase of nanoparticle load (volume fraction) from 0.10% to 9.00%, conductivity of the nanocomposite membrane increases from 9.43 × 10 -9 to 1.35 x 10-3 S/cm, which can meet demand of antistatic material. Conductivity of the nanocomposite membrane is steady below 150 °C.
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Petrochemical Technology
ISSN: 1000-8144
CN: 11-2361/TQ
Year: 2007
Issue: 5
Volume: 36
Page: 502-506
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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