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author:

Wu, Shao-Hua (Wu, Shao-Hua.) [1] | Sun, Jian-Jun (Sun, Jian-Jun.) [2] | Zhang, De-Feng (Zhang, De-Feng.) [3] | Lin, Zhi-Bin (Lin, Zhi-Bin.) [4] | Nie, Fa-Hui (Nie, Fa-Hui.) [5] | Qiu, He-Yuan (Qiu, He-Yuan.) [6] | Chen, Guo-Nan (Chen, Guo-Nan.) [7]

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EI

Abstract:

A single-sided heated graphite cylindrical electrode (ss-HGCE) was designed. Compared to previous alternative current (AC) heating, much simpler and cheaper direct current (DC) heating supplier was adopted for the first time to perform adsorptive accumulation of rutin at ss-HGCE at elevated electrode temperature. This offers great promise for low cost, miniaturization and high compatibility with portability. The square wave voltammetry (SWV) stripping peak current was enhanced with increasing the electrode temperature only during preconcentration step. This enhancement was contributed to the forced thermal convection induced by heating the electrode rather than the bulk solution, which is able to improve mass transfer and facilitate adsorption hence enhance stripping response. A detection limit of 1.0 × 10-9 M (S/N=3) could be obtained at an electrode temperature of 48C during 5 min accumulation, one magnitude lower than that at 28C (room temperature). This is the lowest value at carbon-based electrodes for rutin determination as we know. Such novel method was also successfully used to determine rutin in pharmaceutical tablets. © 2008 Elsevier Ltd. All rights reserved.

Keyword:

Alcohols Drug products Electrochemical electrodes Graphite Graphite electrodes Heat convection Heating Mass transfer Voltammetry

Community:

  • [ 1 ] [Wu, Shao-Hua]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 2 ] [Sun, Jian-Jun]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 3 ] [Zhang, De-Feng]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 4 ] [Lin, Zhi-Bin]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 5 ] [Nie, Fa-Hui]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 6 ] [Qiu, He-Yuan]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China
  • [ 7 ] [Chen, Guo-Nan]Key Laboratory of Analysts and Detection Technology for Food Safety, Ministry of Education, Fuzhou University, 523 Gong Ye Road, Fuzhou 350002, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2008

Issue: 22

Volume: 53

Page: 6596-6601

3 . 0 7 8

JCR@2008

5 . 5 0 0

JCR@2023

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 35

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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