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author:

Wang, Can-Yao (Wang, Can-Yao.) [1] | Zheng, Yu-Ying (Zheng, Yu-Ying.) [2]

Indexed by:

EI PKU CSCD

Abstract:

The Kevlar fiber, treated with tokiene-2, 4-diisocyanate and caprolactam, was used to reinforce MC nylon 6. XPS showed the change in chemical components and spectra after fiber was treated. IR showed that the spectra of Kevlar fiber and MC-nylon 6 were incorporated purely when they were mixed, while the treated Kevlar fiber provided the activation in the ring-opening polymerization of caprolactam, and the amide groups of graft chains could form strong hydrogen bonds with matrix These graft chains and hydrogen bonds would contribute to improving interfacial bonding between MC-nylon 6 and Kevlar fiber. XRD indicated that the induction of Kevlar fiber had no effect on the crystalline style of MC-nylon 6 obviously, however, the crystals had better seasonal structure. The crystals of MC-nylon 6/Kevlar fiber composites were more perfect than that of MC-nylon 6/Kevlar untreated fiber composites with the same amount of Kevlar fiber. The increase of Kevlar fiber contributed to forming perfect α spherulite when the mass concentration of Kevlar fiber was less than 2%, however, the more the Kevlar fiber, the less the content of α spherulite when the mass concentration of Kevlar fiber was more than 2%.

Keyword:

Composite materials Crystalline materials Crystals Hydrogen bonds Nylon polymers Polymerization Spectrum analysis Structure (composition) X ray diffraction X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Wang, Can-Yao]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Zheng, Yu-Ying]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

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Source :

Spectroscopy and Spectral Analysis

ISSN: 1000-0593

Year: 2008

Issue: 1

Volume: 28

Page: 94-97

0 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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