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A nano-sized powder of 3% (mole fraction) yttria stabilized tetragonal zirconia (3Y-TZP) was prepared by a co-precipitation method. The physical and chemical properties of 3Y-TZP powders were characterized by X-ray diffraction, N2 adsorption-desorption isotherms and transmission electron microscope, respectively. The sintering curve of the nano-sized powder of 3Y-TZP, the densification behavior and microstructure of the sintered bulk were analyzed, and the influence of two-step sintering on the microstructure of the 3Y-TZP ceramics was discussed. The results show that the well-developed crystal and agglomeration-free nano-sized powder with the grain size of 13 nm was obtained by co-precipitation method and the subsequent calcination at 600°C for 2 h. The relative density of the 3Y-TZP ceramics was >98% and the grain size was 100 nm when the green body was calcined at 1200°C for 1 min and then decreased to 1050°C for 35 h using two-step sintering method. It was found that the grain growth was inhibited and the densification of the samples was achieved through controlling the calcining temperature and holding time in the two-step sintering process utilizing the different migration kinetics between the grain boundary diffusion and the grain boundary migration. Finally, the sintered body had a full density without any grain growth.
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Journal of the Chinese Ceramic Society
ISSN: 0454-5648
CN: 11-2310/TQ
Year: 2012
Issue: 3
Volume: 40
Page: 335-339
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 3
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