• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Long, Zhen (Long, Zhen.) [1] | Wei, Xian-Hua (Wei, Xian-Hua.) [2] | Qiu, Xiao-Qing (Qiu, Xiao-Qing.) [3]

Indexed by:

EI PKU CSCD

Abstract:

Pure SrTiO3 cubes with perovskite structure were prepared by a molten salt method. The novel visible light active photocatalysts were obtained as a result of surface modification of SrTiO3 cubes with Cu ions by an impregnation technique. The as-prepared samples were characterized by an inductively coupled plasma atomic emission spectrometer, X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscope (XPS), and UV-Vis diffuse reflectance spectroscope (DRS). The decomposition of gaseous 2-propanol was chosen as a probe to evaluate the photocatalytic activities of the samples in air. The results show that the visible light photocatalytic activities of the samples can be significantly enhanced by grafting amorphous Cu(II) clusters on the surfaces of SrTiO3. Under visible light irradiation, electrons in the valance band of SrTiO3 are transferred to the surfaced Cu(II) clusters, leaving holes with strong oxidizing power in the valance band and producing Cu(I) clusters. The Cu(I) clusters can efficiently reduction oxygen molecules via a multi-electron reduction process to consume the excited electrons. On the other hand, the generated holes can decompose the organic compounds. As a result, the complete decomposition of gaseous 2-propanol into CO2 can be achieved over the Cu(II)-SrTiO3 under visible light irradiation.

Keyword:

Copper compounds Decomposition Electrons Fused salts Geometry Heavy ions Inductively coupled plasma Irradiation Light Perovskite Photocatalysis Photocatalytic activity Reduction Scanning electron microscopy Strontium titanates Surface treatment

Community:

  • [ 1 ] [Long, Zhen]State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, China
  • [ 2 ] [Wei, Xian-Hua]State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, China
  • [ 3 ] [Qiu, Xiao-Qing]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

Show more details

Related Keywords:

Source :

Journal of Inorganic Materials

ISSN: 1000-324X

Year: 2013

Issue: 10

Volume: 28

Page: 1103-1107

0 . 5 3 7

JCR@2013

1 . 7 0 0

JCR@2023

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:49/10153896
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1