Indexed by:
Abstract:
Based on the available experimental data, the Bi-Er and the Bi-Dy binary systems have been assessed thermodynamically using the CALPHAD (CALculaton of PHAse Diagram) technique. The formation enthalpies at 0 K of the compounds, Bi3Er5, BiEr, Bi3Dy5 and BiDy, were calculated by the first-principles method and Birch-Murnaghan equation of state, and the calculated results were used in the present thermodynamic optimization. All these compounds in the Bi-Er and the Bi-Dy systems were treated as stoichiometric compounds. The liquid phase was modeled as a substitutional solution phase based on random mixing of the constituent atoms and the excess Gibbs energy was formulated with the Redlich-Kister polynomial. Good agreements were obtained between the calculated results and the experimental data for both the thermochemical properties and the phase equilibrium relations. © 2013 Elsevier B.V. All rights reserved.
Keyword:
Reprint 's Address:
Email:
Source :
Thermochimica Acta
ISSN: 0040-6031
Year: 2013
Volume: 566
Page: 44-49
2 . 1 0 5
JCR@2013
3 . 1 0 0
JCR@2023
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: